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The purpose of this paper is to introduce and analyze a new blast-wave impact-mitigation concept using advanced computational methods and tools. The concept involves the use of a protective structure consisting of bimolecular reactants displaying a number of critical characteristics, including: a high level of thermodynamic stability under ambient conditions (to ensure a long shelf-life of the protective structure); the capability to undergo fast/large-yield chemical reactions under blast-impact induced shock-loading conditions; large negative activation and reaction volumes to provide effective attenuation of the pressure-dominated shockwave stress field through the volumetric-energy storing effects; and a large activation energy for efficient energy dissipation. The case of a particular bimolecular chemical reaction involving polyvinyl pyridine and cyclohexyl chloride as reactants and polyvinyl pyridinium ionic salt as the reaction product is analyzed.

Direct simulations of single planar shockwave propagations through the reactive mixture are carried out, and the structure of the shock front examined, as a function of the occurrence of the chemical reaction. To properly capture the shockwave-induced initiation of the chemical reactions during an impact event, all the calculations carried out in the present work involved the use of all-atom molecular-level equilibrium and non-equilibrium reactive molecular-dynamics simulations. In other words, atomic bonding is not pre-assigned, but is rather determined dynamically and adaptively using the concepts of the bond order and atomic valence.

The results obtained clearly reveal that when the chemical reactions are allowed to take place at the shock front and in the shockwave, the resulting shock front undergoes a considerable level of dispersion. Consequently, the (conserved) linear momentum is transferred (during the interaction of the protective-structure borne shockwaves with the protected structure) to the protected structure over a longer time period, while the peak loading experienced by the protected structure is substantially reduced.

To the authors’ knowledge, the present work is the first attempt to simulate shock-induced chemical reactions at the molecular level, for purposes of blast-mitigation.

The purpose of this paper is to model a nacre-like composite material, consisting of tablets and polyurea tablet/tablet interfaces, B₄C. This composite material is being considered in the construction of the so-called backing-plate, a layer within a multi-functional/multi-layer armor system.

Considering the basic functions of the backing-plate (i.e. to provide structural support for the ceramic-strike-face and to stop a high-velocity projectile and the accompanying fragments) in such an armor system, the composite-material architecture is optimized with respect to simultaneously achieving high flexural stiffness and high ballistic-penetration resistance. Flexural stiffness and penetration resistance, for a given architecture of the nacre-like composite material, are assessed using a series of transient non-linear dynamics finite-element analyses. The suitability of the optimized composite material for use in backing-plate applications is then evaluated by comparing its performance against that of the rolled homogeneous armor (RHA), a common choice for the backing-plate material.

The results obtained established: a trade-off between the requirements for a high flexural stiffness and a high ballistic-penetration resistance in the nacre-like composite material; and overall superiority of the subject composite material over the RHA when used in the construction of the backing-plate within multi-functional/multi-layer armor systems.

This study extends the authors previous research on nacre-mimetic armor to optimize the architecture of the armor with respect to its flexural stiffness and ballistic-penetration resistance, so that these properties could be increased over the levels attained in the current choice (RHA) for the backing layer of multi-functional/multi-layer armor.

This study investigates the ex-dividend day stock prices of the firms listed on the Dhaka Stock Exchange (DSE) where the tax rate is higher on dividends than on capital gains. The results help to explain what impact taxes have on the ex-day stock prices behavior in an emerging market.

To examine the tax effect on the ex-day stock prices behavior, this study considers after-tax dividends and computes the raw price ratio, market-adjusted price ratio, raw price drop, market-adjusted price drop. The market-adjusted ex-dividend day abnormal returns and relative trading volume are also examined to determine the direction of investor trading around the ex-day.

The main hypotheses examine whether the mean (median) differs from its theoretical value by using a t-test and nonparametric sign-rank test. The findings suggest that the drop of stock prices on the ex-day on the DSE is not due to taxes or transaction costs but to valuation assumptions made by investors in determining the equilibrium stock price.

Findings of this study will be useful for investors and traders in their valuation assumption to trade around the ex-dividend day.

Market participant’s preference of dividends, and exempted tax and its ultimate contribution to the equity value explain the ex-day stock prices behavior in the Dhaka Stock Exchange.

Nacre is a biological material constituting the innermost layer of the shells of gastropods and bivalves. It consists of polygonal tablets of aragonite, tessellated to form individual layers and having the adjacent layers as well as the tablets within a layer bonded by a biopolymer. Due to its highly complex hierarchical microstructure, nacre possesses an outstanding combination of mechanical properties, the properties which are far superior to the ones that are predicted using techniques such as the rule of mixtures. Given these properties, a composite armor the structure of which mimics that of nacre may have improved performance over a monolithic armor having a similar composition and an identical areal density. The paper aims to discuss these issues.

In the present work, an attempt is made to model a nacre-like composite armor consisting of B₄C tablets and polyurea tablet/tablet interfaces. The armor is next tested with respect to impact by a solid right circular cylindrical (SRCC) rigid projectile, using a transient non-linear dynamics finite-element analysis. The ballistic-impact response and the penetration resistance of the armor are then compared with that of the B₄C monolithic armor having an identical areal density. Furthermore, the effect of various nacre microstructural features (e.g. surface profiling, micron-scale asperities, mineral bridges between the overlapping tablets lying in adjacent layers, and B₄C nano-crystallinity) on the ballistic-penetration resistance of the composite armor is investigated in order to identify an optimal nacre-like composite armor architecture having the largest penetration resistance.

The results obtained clearly show that a nacre-like armor possesses a superior penetration resistance relative to its monolithic counterpart, and that the nacre microstructural features considered play a critical role in the armor-penetration resistance.

The present work indicates that for a given choice of armor material, penetration resistance may be improved by choosing a structure resembling that of nacre.

The purpose of this paper is to gain insight into justice-involved women’s preferences for an internet-based Sexual Health Empowerment (SHE) curriculum.

The authors analyzed data from four focus groups conducted with 52 women in a minimum-security county jail in a Midwestern US city.

Women reported daily access to the internet while in the community and use of the internet for searching about health concerns. Four themes emerged in the discussion about preferences for an internet-based SHE curriculum, that it cover healthy sexual expression, how to access resources, video as an educational modality and a non-judgmental approach.

Justice-involved women are potentially reachable through internet-based health education. Their preferences for content and modality can be used to inform internet-based sexual health programming designed specifically for this population. Using this modality could offer easily disseminated, low-cost and consistent messaging about sexual health for a vulnerable group of women.

Though internet-based health education programming has been widely utilized in the general population, less attention has been paid to if and how these programs could be utilized with a vulnerable group of women who move between the justice system and communities. This exploratory study begins to fill that gap.

The purpose of this paper is to address the problems of interaction of tensile stress-waves with polyurea/fused-silica and fused-silica/polyurea interfaces, and the potential for the accompanying interfacial decohesion.

The problems are investigated using all-atom non-equilibrium molecular-dynamics methods and tools. Before these methods/tools are employed, previously determined material constitutive relations for polyurea and fused-silica are used, within an acoustic-impedance-matching procedure, to predict the outcome of the interactions of stress-waves with the material-interfaces in question. These predictions pertain solely to the stress-wave/interface interaction aspects resulting in the formation of transmitted and reflected stress- or release-waves, but do not contain any information regarding potential interfacial decohesion. Direct molecular-level simulations confirmed some of these predictions, but also provided direct evidence of the nature and the extent of interfacial decohesion. To properly model the initial state of interfacial cohesion and its degradation during stress-wave-loading, reactive forcefield potentials are utilized.

Direct molecular-level simulations of the polyurea/fused-silica interfacial regions prior to loading revealed local changes in the bonding structure, suggesting the formation of an interphase. This interphase was subsequently found to greatly affect the polyurea/fused-silica decohesion strength.

To the authors’ knowledge, the present work is the first public-domain report of the use of the non-equilibrium molecular dynamics and reactive force-field potentials to study the problem of interfacial decohesion caused by the interaction of tensile waves with material interfaces.

The purpose of this paper is to study the mechanical response of polyurea, soda-lime glass (glass, for short), polyurea/glass/polyurea and glass/polyurea/glass sandwich structures under dynamic-loading conditions involving propagation of planar longitudinal shockwaves.

The problem of shockwave generation, propagation and interaction with material boundaries is investigated using non-equilibrium molecular dynamics. The results obtained are used to construct basic shock Hugoniot relationships associated with the propagation of shockwaves through a homogeneous material (polyurea or glass, in the present case). The fidelity of these relations is established by comparing them with their experimental counterparts, and the observed differences are rationalized in terms of the microstructural changes experienced by the shockwave-swept material. The relationships are subsequently used to predict the outcome of the interactions of shockwaves with polyurea/glass or glass/polyurea material boundaries. Molecular-level simulations are next used to directly analyze the same shockwave/material-boundary interactions.

The molecular-level simulations suggested, and the subsequent detailed microstructural analyses confirmed, the formation of topologically altered interfacial regions, i.e. polyurea/glass and glass/polyurea interphases.

To the authors’ knowledge, the present work is a first attempt to analyze, using molecular-level simulation methods, the interaction of shockwaves with material boundaries.

The purpose of this paper is to propose a computational approach to establish the effect of various flow drilling screw (FS) process and material parameters on the quality and the mechanical performance of the resulting FS joints.

Toward that end, a sequence of three distinct computational analyses is developed. These analyses include: (a) finite-element modeling and simulations of the FS process; (b) determination of the mechanical properties of the resulting FS joints through the use of three-dimensional, continuum finite-element-based numerical simulations of various mechanical tests performed on the FS joints; and (c) determination, parameterization and validation of the constitutive relations for the simplified FS connectors, using the results obtained in (b) and the available experimental results. The availability of such connectors is mandatory in large-scale computational analyses of whole-vehicle crash or even in simulations of vehicle component manufacturing, e.g. car-body electro-coat paint-baking process. In such simulations, explicit three-dimensional representation of all FS joints is associated with a prohibitive computational cost.

Virtual testing of the shell components fastened using the joint connectors validated the ability of these line elements to realistically account for the strength, ductility and toughness of the three-dimensional FS joints.

The approach developed in the present work can be used, within an engineering-optimization procedure, to adjust the FS process and material parameters (design variables) in order to obtain a desired combination of the FS-joint mechanical properties (objective function).

Friction stir welding (FSW) butt-joining involving the use of a dissimilar filler metal insert between the retreating and advancing portions of the workpiece is investigated computationally using a combined Eulerian-Lagrangian (CEL) finite element analysis (FEA). The emphasis of the computational analysis was placed on the understanding of the inter-material mixing and weld-flaw formation during a dissimilar-material FSW process. The paper aims to discuss these issues.

The FEA employed is of a two-way thermo-mechanical character (i.e. frictional-sliding/plastic-work dissipation was taken to act as a heat source in the energy conservation equation), while temperature is allowed to affect mechanical aspects of the model through temperature-dependent material properties. Within the analysis, the workpiece and the filler-metal insert are treated as different materials within the Eulerian subdomain, while the tool was treated as a conventional Lagrangian subdomain. The use of the CEL formulation within the workpiece insert helped avoid numerical difficulties associated with excessive Lagrangian element distortion.

The results obtained revealed that, in order to obtain flaw-free FSW joints with properly mixed filler and base materials, process parameters including the location of the tool relative to the centerline of the weld must be selected judiciously.

To the authors’ knowledge, the present work is the first reported attempt to simulate FSW of dissimilar materials.